Beauty of Joseon Relief Sun Aqua-Fresh Rice + B5 SPF 50+ Versus SKIN1004 Madagascar Centella Probio-Cica Glow Sun Ampoule SPF50+ PA++++

Beauty of Joseon Relief Sun Aqua-Fresh Rice + B5 SPF 50+ Versus SKIN1004 Madagascar Centella Probio-Cica Glow Sun Ampoule SPF50+ PA++++

This chemical sunscreen covers the full UV range and blocks ~98% of UVB at SPF 50.

What's inside

Key Ingredients

Benefits

Concerns

Ingredients Side-by-side

Water

Oryza Sativa Seed Water

Dibutyl Adipate

Butyloctyl Salicylate

Ethylhexyl Triazone

1,2-Hexanediol

Drometrizole Trisiloxane

Polyglyceryl-3 Distearate

Terephthalylidene Dicamphor Sulfonic Acid

Diethylamino Hydroxybenzoyl Hexyl Benzoate

Polymethylsilsesquioxane

Tromethamine

Panthenol

Pentylene Glycol

Glyceryl Stearate

Silica

Caprylyl Methicone

Avena Sativa Kernel Extract

Cynara Scolymus Leaf Extract

Camellia Sinensis Leaf Water

Hydrogenated Lecithin

Oryza Sativa Bran Oil

Sodium Hyaluronate

Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine

Propanediol

Potassium Cetyl Phosphate

Poly C10-30 Alkyl Acrylate

Methylpropanediol

Carbomer

Acrylates/C10-30 Alkyl Acrylate Crosspolymer

Ethylhexylglycerin

Xanthan Gum

Glycerin

Polyether-1

Polyquaternium-51

Beta-Glucan

Biosaccharide Gum-1

Inositol

Tocopherol

Ferulic Acid

Citric Acid

Ceramide NP

Phytosphingosine

Rice Amino Acids

Rice Sh-Oligopeptide-1

Water, Oryza Sativa Seed Water, Dibutyl Adipate, Butyloctyl Salicylate, Ethylhexyl Triazone, 1,2-Hexanediol, Drometrizole Trisiloxane, Polyglyceryl-3 Distearate, Terephthalylidene Dicamphor Sulfonic Acid, Diethylamino Hydroxybenzoyl Hexyl Benzoate, Polymethylsilsesquioxane, Tromethamine, Panthenol, Pentylene Glycol, Glyceryl Stearate, Silica, Caprylyl Methicone, Avena Sativa Kernel Extract, Cynara Scolymus Leaf Extract, Camellia Sinensis Leaf Water, Hydrogenated Lecithin, Oryza Sativa Bran Oil, Sodium Hyaluronate, Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine, Propanediol, Potassium Cetyl Phosphate, Poly C10-30 Alkyl Acrylate, Methylpropanediol, Carbomer, Acrylates/C10-30 Alkyl Acrylate Crosspolymer, Ethylhexylglycerin, Xanthan Gum, Glycerin, Polyether-1, Polyquaternium-51, Beta-Glucan, Biosaccharide Gum-1, Inositol, Tocopherol, Ferulic Acid, Citric Acid, Ceramide NP, Phytosphingosine, Rice Amino Acids, Rice Sh-Oligopeptide-1

Niacinamide

Vp/Hexadecene Copolymer

Sodium Polyacryloyldimethyl Taurate

Sodium Acrylate/Sodium Acryloyldimethyl Taurate Copolymer

Hydrogenated Poly(C6-14 Olefin)

Centella Asiatica Extract

Betaine

Hydroxypropyl Methylcellulose Stearoxy Ether

Ammonium Polyacryloyldimethyl Taurate

Adenosine

Glyceryl Stearate Citrate

Laminaria Japonica Extract

Ulmus Davidiana Root Extract

Aloe Barbadensis Leaf Extract

Viola Tricolor Extract

Dioscorea Japonica Root Extract

Lauryl Glucoside

Butylene Glycol

T-Butyl Alcohol

Caprylic/Capric Triglyceride

Macadamia Integrifolia Seed Oil

Hydroxystearic Acid

Lactobacillus Ferment

Madecassic Acid

Asiaticoside

Polyglyceryl-10 Myristate

Asiatic Acid

Sucrose Distearate

Lauric Acid

Phytosterols

Water, Dibutyl Adipate, Butyloctyl Salicylate, Ethylhexyl Triazone, Diethylamino Hydroxybenzoyl Hexyl Benzoate, Propanediol, Niacinamide, Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine, Terephthalylidene Dicamphor Sulfonic Acid, 1,2-Hexanediol, Poly C10-30 Alkyl Acrylate, Glycerin, Tromethamine, Panthenol, Vp/Hexadecene Copolymer, Sodium Polyacryloyldimethyl Taurate, Polyglyceryl-3 Distearate, Sodium Acrylate/Sodium Acryloyldimethyl Taurate Copolymer, Hydrogenated Poly(C6-14 Olefin), Centella Asiatica Extract, Betaine, Hydroxypropyl Methylcellulose Stearoxy Ether, Ammonium Polyacryloyldimethyl Taurate, Ethylhexylglycerin, Adenosine, Glyceryl Stearate Citrate, Laminaria Japonica Extract, Ulmus Davidiana Root Extract, Aloe Barbadensis Leaf Extract, Viola Tricolor Extract, Dioscorea Japonica Root Extract, Lauryl Glucoside, Butylene Glycol, T-Butyl Alcohol, Caprylic/Capric Triglyceride, Hydrogenated Lecithin, Macadamia Integrifolia Seed Oil, Hydroxystearic Acid, Ceramide NP, Lactobacillus Ferment, Madecassic Acid, Asiaticoside, Polyglyceryl-10 Myristate, Phytosphingosine, Asiatic Acid, Sucrose Distearate, Lauric Acid, Phytosterols

Reviews

Alternatives

Ingredients Explained

These ingredients are found in both products.

Ingredients higher up in an ingredient list are typically present in a larger amount.

1,2-Hexanediol is a synthetic liquid and another multi-functional powerhouse.

It is a:

Humectant, drawing moisture into the skin

Emollient, helping to soften skin

Solvent, dispersing and stabilizing formulas

Preservative booster, enhancing the antimicrobial activity of other preservatives

This ingredient is better known as bemotrizinol or Tinosorb S and is one of the best broad-spectrum UV filters in modern sunscreen.

It works by absorbing UV light across a whole range (280-400 nm) with peaks around 310 nm (UVB) and 340-345 nm (UVA). This means it covers UVB plus the deeper UVA wavelengths that drive photoaging and pigmentation.

Another pro?

It's exceptionally photostable, barely degrades in sunlight, and acts as a "bodyguard" for less stable filters.

That's why you'll see it paired with avobenzone or octinoxate; this team up ensures they keep working through sun exposure.

Safety reviews have been reassuring across the board. This ingredient shows low absorption through the skin, rarely irritates, and lab studies found it doesn't act like a hormone in the body (a concern that's been raised about some older sunscreen filters).

On maximum concentrations:

In 2026, the US F.D.A finally added it as an OTC sunscreen ingredient at concentrations up to 6% for adults / children 6 months and older

Butyloctyl Salicylate is a chemical UV filter structurally similar to octisalate. It is a photostabilizer, SPF booster, emollient and solvent. This ingredient helps evenly spread out ingredients.

According to a manufacturer, it is suitable for pairing with micro Titanium Dioxide, Zinc Oxide, and pigments.

Photostabilizers help stabilize UV-filters and prevents them from degrading quickly.

Ceramide NP (formerly known as Ceramide 3) is one of the skin's naturally occurring lipids.

Since ceramides are the major lipid components of the skin, they are crucial for maintaining skin barrier and hydration. Ceramide NP most closely mirrors the dominant kind in human skin amongst ceramide subtypes.

This ceramide works by slotting into gaps within the stratum corneum's lipid matrix to limit trans-epidermal water loss (TEWL) and shield the skin against external irritants.

A study with 312 patients found that using a ceramide-containing routine for 4 weeks reduced the severity of atopic dermatitis by over 61%.

Another clinical study in subjects aged 60 and older found that a ceramide body wash and moisturizer improved skin dryness and itchy skin in 15 days.

Overall, ceramides are considered non-irritating and safety tests have found little to no observable adverse effects from using this ingredient.

Ceramide NP is usually sourced from plants (like soybean or rice bran), or produced synthetically.

Dibutyl Adipate is a lightweight, oil-soluble ester that acts as an emollient and solvent. It helps products spread more easily and leaves a soft, silky, dry-touch finish without being greasy.

You'll likely see this ingredient in sunscreens because it does a nice job dissolving UV filters and keeping them evenly distributed.

This ingredient has been found to be safe as used in cosmetics, wasn't a skin or eye irritant in clinical patch testing, and wasn't phototoxic.

In a clinical comedogenicity test, this ingredient tested negative so it isn't likely to clog pores.

Typical use levels are about 5-8% for sunscreens + nail products, but can range from 0.005%-8% depending on the product.

Diethylamino Hydroxybenzoyl Hexyl Benzoate (DHHB) is a chemical UV-A absorber. It is formulated for high UVA protection (320-400 nm).

DHHB is well-liked for:

DHHB has been approved by the EU, Japan, Taiwan, and South America for use up to 10%. Unfortunately, it has not been approved for use in the US or Canada due to slow regulatory processes.

This ingredient is soluble in oils, fats, and lipids.

Ethylhexyl Triazone (aka Octyl Triazone) is an oil-soluble organic UVB filter. It has peak absorption around 314 nm, right in the middle of the UVB range.

This ingredient is described as one of the most effective UVB filters available and small concentrations are enough to deliver a high SPF thanks to its strong UV absorbing power.

Formulators love it for its stability; its ability to filter UV stays practically unchanged even under intense radiation and it can also help boost the photostability of less stable filters like avobenzone.

It's also a great pick for water resistant products because it's insoluble in water and has a good affinity for keratin.

Because it's a big, heavy molecule, the European Scientific Committee has found to to have very low dermal penetration and negative results for allergenicity.

In vitro testing also showed a low absorption rate and clean results on irritation.

Typical use levels are 1-5% with 5% being the maximum in the EU, Japan, and other markets that allow it. However, this ingredient is not approved yet in the US or Canada.

Ethylhexylglycerin is created from glycerin. It is a multitasker ingredient that:

The CIR Expert Panel found minimal skin absorption or sensitization of any kind in a safety assessment. Though this ingredient is considered well-tolerated, a small number of cases of allergic dermatitis have been published since 2002. Just be sure to patch test if you are unsure.

Industry-reported use ranges from 8% in rinse-off products and 2% in leave-on formulations.

Glycerin (or glycerol) is a compound naturally found in your skin. It's a powerhouse humectant that pulls water into the stratum corneum.

Topically, glycerin does several things at once:

Your skin makes glycerin on its own (mostly from sebaceous oil breakdown) and shuttles it to your outermost layer of skin, or your epidermis, via aquaporin-3.

Aquaporin-3 is a transporter that is essential for normal skin hydration, elasticity, and repair. Interestingly, mice lacking in AQP3 have dry and less elastic skin that can be fully corrected with glycerin.

This ingredient is non-irritating, plays well with almost every ingredient, and works across all skin types. Typical use is anywhere between 3-10% but can go up to 79% in some leave-on products.

Just know very high concentrations (>40%) can feel tacky in low humidity.

Glycerin is the name for this ingredient in American English. British English uses Glycerol/Glycerine.

Hydrogenated Lecithin is a more stable version of lecithin.

It's made by taking lecithin (a phospholipid commonly found in soybeans and egg yolks) and hydrogenating it. This just means the unsaturated fatty acids are turned into saturated ones so they don't go bad as easily.

This ingredient is an emollient, emulsifier, and penetration enhancer. As an emollient, it helps soften and hydrate skin by trapping moisture within. As an emulsifier, it prevents oil and water ingredients from separating.

Hydrogenated Lecithin can form tiny spherical structures made of phospholipid bilayers called liposomes. These liposomes are able to capture compounds inside their structure and deliver them through the skin barrier.

Because phospholipids are a natural component of our cell membranes, this ingredient is inherently compatible with skin.

A 2021 study found lecithin-based surfactants were less harsh and more tolerable comared to Sodium Lauryl Sulfate (SLS).

Panthenol is a common ingredient that helps hydrate and soothe the skin. It is found naturally in our skin and hair.

There are two forms of panthenol: D and L.

D-panthenol is also known as dexpanthenol. Most cosmetics use dexpanthenol or a mixture of D and L-panthenol.

Panthenol is famous due to its ability to go deeper into the skin's layers. Using this ingredient has numerous pros (and no cons):

Like hyaluronic acid, panthenol is a humectant. Humectants are able to bind and hold large amounts of water to keep skin hydrated.

This ingredient works well for wound healing. It works by increasing tissue in the wound and helps close open wounds.

Once oxidized, panthenol converts to pantothenic acid. Panthothenic acid is found in all living cells.

This ingredient is also referred to as pro-vitamin B5.

Phytosphingosine is a phospholipid naturally found in our skin as a building block for ceramides.. It helps moisturize, soothe, and protect skin.

Phytosphingosine contributes to your skin's natural moisturizing factor (NMF). The NMF is responsible for hydration, a strong barrier, and plasticity. Our NMF decreases with age. Increasing NMF leads to more healthy and hydrated skin.

Studies show products formulated with NMF ingredients help strengthen our skin's barrier. Having a healthy skin barrier reduces irritation and increases hydration. Our skin barrier is responsible for having plump and firm skin. It also helps protect our skin against infection, allergies, and inflammation.

Fun fact: Phytosphingosine is abundant in plants and fungi.

More ingredients that help boost collagen in skin:

Poly C10-30 Alkyl Acrylate is a synthetic polymer. It's a long chain built from acrylic acid units and each unit carries a fatty "tail" derived form a C10-30 alcohol.

Those oil-loving tails allow this ingredient to thicken oil phases, hold emulsions together, and cuts the tacky/greasy feel of heavy formulas.

Typical use levels sit around 0.1-3%, with 0.3-3% more common in leave-on emulsions.

This ingredient was reviewed as part of a group of 126 acrylates and concluded to be safe by the Cosmetic Ingredient Review Expert Panel.

Though acrylate contact allergy is real and well-documented, allergy risk is quite low. The cases of documented contact allergy are caused by unreacted monomers (more commonly found in gel nails, dental resins, and adhesives).

Polyglyceryl-3 Distearate isn't fungal acne safe.

Propanediol is an all-star ingredient. It softens, hydrates, and smooths the skin.

It’s often used to:

Propanediol is not likely to cause sensitivity and considered safe to use. It is derived from corn or petroleum with a clear color and no scent.

Terephthalylidene Dicamphor Sulfonic Acid (aka ecamsule or Mexoryl SX) is a water-soluble organic UV filter developed and patented by L'Oreal back in 1982.

It's one of the better UVA protectors out there and shields skin across a broad UVA range (~290-390 nm) with peak absorption right around 345 nm.

This peak absorption happens to be the exact type of UVA light that sinks deepest into skin and does the most to cause aging and dark spots.

Ecamsule works by soaking up UV rays and turning them into a tiny bit of harmless heat. The molecule basically flips, releases that energy as heat, then snaps back to its original shape and does it all over again. This is also why it's so stable in sunlight and doesn't break down or wear out the way some filters do.

The clinical backing for this ingredient is solid as well:

A large 2008 review by Fourtanier & colleagues (2008) pulled together human trials showing ecamsule-containing sunscreens prevented UV-induced pigmentation, DNA damage, and signs of aging.

That built on earlier work by Seite et al. (1998) that found it protected skin from repeated low-level UVA exposure. And a controlled study by DeLeo et al. (2009) showed that even an SPF 40 cream with ecamsule helped prevent sun-triggered rash even under the real sun.

On concentrations:

Because this ingredient is an acid, it has to be neutralized so it doesn't tank the product's pH.

Safety-wise, it's pretty well tolerated. There are some rare cases of mild irritation mostly in people with sensitivities towards camphor derivatives.

A 2019 FDA study found that volunteers who slathered on sunscreen heavily for several days had tiny amounts of ecamsule show up in their blood. This was slightly above the level at which the FDA asks for extra safety testing; this just means the FDA wants more safety studies done and not evidence that anything harmful actually happens. No problems were found and dermatologists still recommend using sunscreen.

Tromethamine (aka THAM) is a synthetic amino acid that shows up in skincare as a helper ingredient.

It functions as a pH adjuster to help neutralize acidic ingredients and set a formula's pH to the right spot.

This matters a lot because a lot of actives (like vitamin C) needs a specific pH to work well and feel comfortable on skin.

Concentration use ranges from 0.1-1.0% depending on the formula.

Water. It's the most common cosmetic ingredient of all. You'll usually see it at the top of ingredient lists, meaning that it makes up the largest part of the product.

So why is it so popular? Water most often acts as a solvent - this means that it helps dissolve other ingredients into the formulation.

You'll also recognize water as that liquid we all need to stay alive. If you see this, drink a glass of water. Remember to stay hydrated!

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