Shu Uemura Unlimited Block : Booster Hydrating Primer SPF 50+ PA+++ Versus Beauty of Joseon Relief Sun : Rice + Probiotics SPF 50+ PA++++

Shu Uemura Unlimited Block : Booster Hydrating Primer SPF 50+ PA+++ Versus Beauty of Joseon Relief Sun : Rice + Probiotics SPF 50+ PA++++

This chemical sunscreen covers the full UV range and blocks ~98% of UVB at SPF 50.

What's inside

Key Ingredients

Benefits

Concerns

Ingredients Side-by-side

Water

Alcohol Denat.

Ethylhexyl Salicylate

Isononyl Isononanoate

Octocrylene

Butyl Methoxydibenzoylmethane

Ethylhexyl Triazone

Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine

CI 77891

Methylene Bis-Benzotriazolyl Tetramethylbutylphenol

Propanediol

Isopropyl Lauroyl Sarcosinate

Silica

Cetearyl Alcohol

Diisopropyl Sebacate

Coco-Caprylate/Caprate

Mica

Phenoxyethanol

Homosalate

Butylene Glycol

Ammonium Acryloyldimethyltaurate/Vp Copolymer

Polyglyceryl-10 Laurate

Cetearyl Glucoside

Tocopherol

Glycerin

Sodium Stearoyl Glutamate

Caprylyl Glycol

Caramel

Carbomer

Inulin Lauryl Carbamate

Tin Oxide

Propylene Glycol

Adenosine

Trisodium Ethylenediamine Disuccinate

Xanthan Gum

Alumina

Isopropyl Titanium Triisostearate

Sorbitol

Zea Mays Kernel Extract

Nelumbo Nucifera Flower Extract

CI 17200

Paeonia Suffruticosa Root Extract

Sorbic Acid

Citric Acid

Water, Alcohol Denat., Ethylhexyl Salicylate, Isononyl Isononanoate, Octocrylene, Butyl Methoxydibenzoylmethane, Ethylhexyl Triazone, Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine, CI 77891, Methylene Bis-Benzotriazolyl Tetramethylbutylphenol, Propanediol, Isopropyl Lauroyl Sarcosinate, Silica, Cetearyl Alcohol, Diisopropyl Sebacate, Coco-Caprylate/Caprate, Mica, Phenoxyethanol, Homosalate, Butylene Glycol, Ammonium Acryloyldimethyltaurate/Vp Copolymer, Polyglyceryl-10 Laurate, Cetearyl Glucoside, Tocopherol, Glycerin, Sodium Stearoyl Glutamate, Caprylyl Glycol, Caramel, Carbomer, Inulin Lauryl Carbamate, Tin Oxide, Propylene Glycol, Adenosine, Trisodium Ethylenediamine Disuccinate, Xanthan Gum, Alumina, Isopropyl Titanium Triisostearate, Sorbitol, Zea Mays Kernel Extract, Nelumbo Nucifera Flower Extract, CI 17200, Paeonia Suffruticosa Root Extract, Sorbic Acid, Citric Acid

Dibutyl Adipate

Diethylamino Hydroxybenzoyl Hexyl Benzoate

Polymethylsilsesquioxane

Niacinamide

Caprylyl Methicone

Diethylhexyl Butamido Triazone

1,2-Hexanediol

Oryza Sativa Extract

Oryza Sativa Germ Extract

Camellia Sinensis Leaf Extract

Lactobacillus/Pumpkin Ferment Extract

Bacillus/Soybean Ferment Extract

Saccharum Officinarum Extract

Macrocystis Pyrifera Extract

Cocos Nucifera Fruit Extract

Panax Ginseng Root Extract

Monascus/Rice Ferment

Behenyl Alcohol

Poly C10-30 Alkyl Acrylate

Polyglyceryl-3 Methylglucose Distearate

Decyl Glucoside

Tromethamine

Acrylates/C10-30 Alkyl Acrylate Crosspolymer

Polyacrylate Crosspolymer-6

T-Butyl Alcohol

Lactobacillus/Rice Ferment

Aspergillus Ferment

Saccharomyces/Rice Ferment Filtrate

Pentylene Glycol

Ethylhexylglycerin

Water, Dibutyl Adipate, Propanediol, Diethylamino Hydroxybenzoyl Hexyl Benzoate, Polymethylsilsesquioxane, Ethylhexyl Triazone, Niacinamide, Methylene Bis-Benzotriazolyl Tetramethylbutylphenol, Coco-Caprylate/Caprate, Caprylyl Methicone, Diethylhexyl Butamido Triazone, Glycerin, 1,2-Hexanediol, Butylene Glycol, Oryza Sativa Extract, Oryza Sativa Germ Extract, Camellia Sinensis Leaf Extract, Lactobacillus/Pumpkin Ferment Extract, Bacillus/Soybean Ferment Extract, Saccharum Officinarum Extract, Macrocystis Pyrifera Extract, Cocos Nucifera Fruit Extract, Panax Ginseng Root Extract, Monascus/Rice Ferment, Behenyl Alcohol, Poly C10-30 Alkyl Acrylate, Polyglyceryl-3 Methylglucose Distearate, Decyl Glucoside, Tromethamine, Carbomer, Acrylates/C10-30 Alkyl Acrylate Crosspolymer, Sodium Stearoyl Glutamate, Polyacrylate Crosspolymer-6, Adenosine, Xanthan Gum, T-Butyl Alcohol, Tocopherol, Lactobacillus/Rice Ferment, Aspergillus Ferment, Saccharomyces/Rice Ferment Filtrate, Pentylene Glycol, Ethylhexylglycerin

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Alternatives

Ingredients Explained

These ingredients are found in both products.

Ingredients higher up in an ingredient list are typically present in a larger amount.

Adenosine is a purine nucleoside that your body already makes in every cell. In skincare, it acts mainly as a skin conditioning and anti-aging agent.

The way it works is fairly well mapped out:

Your skin has cells called fibroblasts that build collagen (the stuff that keeps skin firm and smooth). Adenosine basically flips a switch on these cells that tells them to get to work making more collagen and other proteins. These cells slow down on their own as skin ages, so Adenosine helps give them a little nudge to keep going.

The clinical backing is pretty solid too.

A blind, randomized, placebo-controlled trial of 126 women aged 45-65 tested a 0.1% cream twice daily and found real improvements in crow's feet and frown lines using a precise 3D skin-mapping technique; these changes showed up by week 3 and held at 2 months.

A later study using Adenosine-loaded dissolving microneedle patches reported gains in wrinkle depth, dermal density, elasticity, and hydration.

On concentrations, South Korea's Ministry of Food and Drug Safety has set 0.04% as the approved functional anti-wrinkle level. You'll typically see this ingredient used somewhere in the 0.04-0.1% range since it works at low doses.

This ingredient has been found safe for cosmetics with the data showing no irritation or sensitization.

Overall, this is a great ingredient for any anti-aging routine and has no photosensitizing effect, so it suits both AM and PM use.

Butylene Glycol (or BG) is used within cosmetic products for a few different reasons:

Overall, Butylene Glycol is a safe and well-rounded ingredient that works well with other ingredients.

Though this ingredient works well with most skin types, some people with sensitive skin may experience a reaction such as allergic rashes, closed comedones, or itchiness.

Carbomer is a synthetic thickening and gelling agent. It's basically the ingredient that gives a lot of serums, gels, creams, and sunscreens their smooth, non-sticky texture.

Although legally permitted at very high levels, carbomers are normally used at concentrations below 1%.

It also needs to be neutralized to actually thicken, and because it is a large molecule, it doesn't really penetrate the skin barrier.

Allergy-wise, the risk is very low. Clinical studies show carbomers have low potential for skin irritation/sensitization even at concentrations up to 100%.

A 2024 UK study patch-tested 1,302 patients and found true allergy to the parent group of carbomer to be rare with no confirmed relevant reactions.

Coco-Caprylate/Caprate is a lightweight ester created from coconut oil fatty acids, caprylic acid, and capric acid.

It is an emollient that helps soften skin and reduce transepidermal water loss (TEWL). What sets it apart from heavier emollients is its ultralight, non-greasy feel.

Once applied, this ingredient dries down quickly and leaves a dry, silky finish behind. This also helps improve spreadability and texture.

This ingredient has an excellent safety-record and is non-irritating.

Typical concentrations for cosmetics range from 0.5-62%.

Research on Malassezia growth found no growth on fatty acid esters with chain lengths shorter than 12 carbons (it prefers C11-24).

Since Coco-Caprylate/Caprate is built on C8 and C10 fatty acids, it is out of the range that Malassezia metabolizes, and therefore safe for fungal acne.

Ethylhexyl Triazone (aka Octyl Triazone) is an oil-soluble organic UVB filter. It has peak absorption around 314 nm, right in the middle of the UVB range.

This ingredient is described as one of the most effective UVB filters available and small concentrations are enough to deliver a high SPF thanks to its strong UV absorbing power.

Formulators love it for its stability; its ability to filter UV stays practically unchanged even under intense radiation and it can also help boost the photostability of less stable filters like avobenzone.

It's also a great pick for water resistant products because it's insoluble in water and has a good affinity for keratin.

Because it's a big, heavy molecule, the European Scientific Committee has found to to have very low dermal penetration and negative results for allergenicity.

In vitro testing also showed a low absorption rate and clean results on irritation.

Typical use levels are 1-5% with 5% being the maximum in the EU, Japan, and other markets that allow it. However, this ingredient is not approved yet in the US or Canada.

Glycerin (or glycerol) is a compound naturally found in your skin. It's a powerhouse humectant that pulls water into the stratum corneum.

Topically, glycerin does several things at once:

Your skin makes glycerin on its own (mostly from sebaceous oil breakdown) and shuttles it to your outermost layer of skin, or your epidermis, via aquaporin-3.

Aquaporin-3 is a transporter that is essential for normal skin hydration, elasticity, and repair. Interestingly, mice lacking in AQP3 have dry and less elastic skin that can be fully corrected with glycerin.

This ingredient is non-irritating, plays well with almost every ingredient, and works across all skin types. Typical use is anywhere between 3-10% but can go up to 79% in some leave-on products.

Just know very high concentrations (>40%) can feel tacky in low humidity.

Glycerin is the name for this ingredient in American English. British English uses Glycerol/Glycerine.

This ingredient is also known as Tinosorb M or Bisoctrizole and is a bit of an overachiever in the sunscreen world.

It's a hybrid broad-spectrum filter that covers UVA and UVB (~280-400nm) with peak absorption around 305nm for UVB or 360nm for UVA (and a tiny bit in blue-light territory as well).

One of its best party tricks is photostability; it doesn't break down with repeated sun exposure and doesn't generate free radicals in the process either. You'll also see it paired with wobbly filters like avobenzone because it helps stabilize them.

The safety profile is assuring as well. Because it's a large molecule, it doesn't easily absorb into skin and rarely causes irritation.

It's approved in the EU, Asia, and Australia up to 10% and most formulas land somewhere in the 2-10% range.

You won't find it as a sunscreen active in the US, but it can make an appearance as a formula-protecting UV-absorber.

Propanediol is an all-star ingredient. It softens, hydrates, and smooths the skin.

It’s often used to:

Propanediol is not likely to cause sensitivity and considered safe to use. It is derived from corn or petroleum with a clear color and no scent.

Sodium Stearoyl Glutamate is an amino-acid based emulsifier. It is made by combining stearic acid with L-glutamic acid and neutralizing it to a sodium salt.

As an emulsifier, it works mainly as an oil-in-water one and helps keep the oil and water in your formulas blended. It also contributes to a smooth, non-greasy skin feel.

This ingredient is biodegradable and commonly available in natural/COSMOS-certified grades.

Tocopherol is a fat-soluble antioxidant known as Vitamin E.

You'll find this ingredient in the vast majority of skincare (for good reason). It works to neutralize free radicals, or unstable molecules generated by UV exposure, pollution, and other environmental stressors, before they can cause oxidative damage to your skin cells.

Topically applied tocopherol has been shown to protect against UV damage by ramping up the skin's own natural defense enzymes.

It also acts as a skin conditioning agent; some studies show that regular topical use can improve the skin's water-binding capacity over 2-4 weeks.

This ingredient is especially loved for being a team player. When combined with Vitamin C, the photoprotective effect of both ingredients roughly doubles and the combo also helps reduce UV-induced DNA damage.

This ingredient has some brightening potential but it's more of a prevention ingredient than spot-fader. Cell studies show it can slow down melanin production but it's worth noting that it's not the most powerful brightener out there.

In formulations, it also serves as a stabilizer that helps protect other oxidation-prone ingredients from degrading.

Concentrations usually range from 0.1-1% in most leave-on products.

Water. It's the most common cosmetic ingredient of all. You'll usually see it at the top of ingredient lists, meaning that it makes up the largest part of the product.

So why is it so popular? Water most often acts as a solvent - this means that it helps dissolve other ingredients into the formulation.

You'll also recognize water as that liquid we all need to stay alive. If you see this, drink a glass of water. Remember to stay hydrated!

Xanthan gum is used as a stabilizer and thickener within cosmetic products. It helps give products a sticky, thick feeling - preventing them from being too runny.

On the technical side of things, xanthan gum is a polysaccharide - a combination consisting of multiple sugar molecules bonded together.

Xanthan gum is a pretty common and great ingredient. It is a natural, non-toxic, non-irritating ingredient that is also commonly used in food products.

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